Assertion (A): An ideal gas is enclosed within a container fitted with a piston when volume of this enclosed gas is increased at constant temperature. The pressure exerted by the gas on the piston decreases.
Reason (R): In the above situation the rate of molecules striking the piston decreases. Therefore pressure exerted by gas on piston decreases.
Solution:
Assertion (A) is true by Boyle's Law (\( PV = \text{constant} \) at constant \( T \)). Reason (R) explains (A) microscopically: increasing volume at constant temperature reduces the density of molecules and thus the frequency of collisions with the piston, leading to decreased pressure.
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