Rankers Physics
Topic: Thermal Physics
Subtopic: Kinetic Theory of Gases

An ideal diatomic gas occupies a volume V1 at a pressure P1 undergoes a process in which the pressure is directly proportional to the volume. At the end of the process the rms speed of gas molecules has doubled from its initial value. Heat supplied to the gas in the given process is :
\[ 7P_{1}V_{1}\]
\[ 8P_{1}V_{1} \]
\[ 9P_{1}V_{1} \]
\[ 10P_{1}V_{1}\]

Solution:

Since the pressure \( P \) is directly proportional to the volume \( V \), we have:

\[
P \propto V \Rightarrow P = kV
\]

where \( k \) is a constant. This process describes a line through the origin on a \( P \)-\( V \) graph, where work \( W \) done by the gas is given by the area under the line:

\[
W = \frac{P_{\text{final}} V_{\text{final}} - P_{\text{initial}} V_{\text{initial}}}{2}
\]

Given that the r.m.s. speed doubles, we know the temperature \( T \) has quadrupled (since \( v_{\text{rms}} \propto \sqrt{T} \)). Therefore:

\[
\frac{T_{\text{final}}}{T_{\text{initial}}} = 4
\]

For an ideal gas, \( PV = nRT \), so if \( T \) quadruples, \( PV \) also quadruples, making \( P_{\text{final}} V_{\text{final}} = 4 P_1 V_1 \).

Using the work formula above:

\[
W = \frac{4 P_1 V_1 - P_1 V_1}{2} = \frac{3 P_1 V_1}{2} = 3 P_1 V_1
\]

The change in internal energy \( \Delta U \) for a diatomic gas (\( C_V = \frac{5}{2}R \)) is:

\[
\Delta U = n C_V \Delta T = \frac{5}{2} (P_1 V_1) \cdot 3 = \frac{15}{2} P_1 V_1 = 7.5 P_1 V_1
\]

Using the first law of thermodynamics \( Q = \Delta U + W \):

\[
Q = 7.5 P_1 V_1 + 3 P_1 V_1 = 9 P_1 V_1
\]

Answer: The heat supplied to the gas is \( 9 P_1 V_1 \).

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