Rankers Physics
Topic: Thermal Physics
Subtopic: Calorimetry

Heat is supplied to a certain homogeneous sample of matter at a uniform rate. Its temperature is plotted against time as shown, which of the following conclusion can be drawn ? Image related to
It's specific heat capacity is greater in the solid state than in liquid state
It's specific heat capacity is greater in the liquid state than in the solid state.
It specific heat capacity in liquid state is equal to that of in solid state.
data insufficient.

Solution:

Given the graph and your observation, we can analyze whether the specific heat capacity is greater in the liquid state than in the solid state.

In a temperature vs. time graph, under uniform heat supply, the slope of the graph during the temperature rise is inversely proportional to the specific heat capacity (\(C\)). Mathematically, for a given heat input rate:

\[
\text{Rate of temperature increase} \propto \frac{1}{C}
\]

- Solid phase: In the first sloped section (just before the first horizontal plateau), the slope is steeper, indicating a faster temperature increase. This implies that the specific heat capacity of the substance in the solid state is lower.

- Liquid phase: After the first plateau (phase change), the slope in the second sloped section (where the substance is in the liquid state) is less steep, indicating a slower temperature increase. This suggests that more heat is required to raise the temperature in this phase, which means the specific heat capacity is higher in the liquid state.

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