Molar Specific Heat of Hydrogen – Rankers Physics
Topic: Thermal Physics
Subtopic: Thermodynamics

Molar Specific Heat of Hydrogen

Assertion (A): Experimental results indicate that the molar specific heat of hydrogen gas at constant volume below \( 50 \text{ K} \) is equal to \( 5/2 R \), where \( R \) is the universal gas constant.
Reason (R): A diatomic hydrogen molecule possesses three translational and two rotational degrees of freedom at all temperatures.
 
Both (A) & (R) are true and the (R) is the correct explanation of the (A)
Both (A) & (R) are true but the (R) is not the correct explanation of the (A)
(A) is true but (R) is false
Both (A) and (R) are false

Solution:

Assertion (A) is false. Below \( 50 \text{ K} \), hydrogen's rotational modes freeze out, so \( C_V \) approaches \( 3/2 R \), not \( 5/2 R \).


Reason (R) is false because degrees of freedom depend on temperature; vibrational modes activate at high T, and rotational modes freeze out at low T.

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