Reason (R): A diatomic hydrogen molecule possesses three translational and two rotational degrees of freedom at all temperatures.
Solution:
Assertion (A) is false. Below \( 50 \text{ K} \), hydrogen's rotational modes freeze out, so \( C_V \) approaches \( 3/2 R \), not \( 5/2 R \).
Reason (R) is false because degrees of freedom depend on temperature; vibrational modes activate at high T, and rotational modes freeze out at low T.
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